(5R)-5-[(1R)-2,2-Dichloro-1-methyl­cyclo­prop­yl]-2-methyl­cyclo­hex-2-en-1-one

نویسندگان

  • Brahim Boualy
  • Mohamed Anoir Harrad
  • Larbi El Firdoussi
  • Mustapha Ait Ali
  • Corrado Rizzoli
چکیده

The title compound, C(11)H(14)Cl(2)O, was synthesized by the reaction of a dichloro-methane solution of (R)-carvone and potassium tert-butano-late in the presence of a catalytic amount of benzyl-triethyl-ammonium chloride in chloro-form. The cyclo-hexene ring adopts a half-boat conformation. The cyclo-propyl ring is unsymmetrical, the shortest C-C bond being distal to the alkyl-substituted C atom. The crystal packing is stabilized only by van der Waals inter-actions.

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011